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Facile C-H bond activation: synthesis of the N 4 C donor set pentadentate ligand 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) and a structural study of its alkyl?cobalt(III) complex [Co(dmpdacn- C )(OH 2 )](ClO 4 ) 2 ⋅H 2 O and its hydroxylated derivative [Co(dmpdacnOH- O )Cl](ClO 4 ) 2 ⋅C 3 H 6 O

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Zhou, Xiangting; Day, Anthony; Edwards, Alison; Willis, Anthony; Jackson, William Gregory

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The 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) ligand with a N4C donor set deprotonates at a CH2 γ to an amine under extraordinarily mild conditions (pH 7) and binds as a pentadentate ligand to Co(III) as the [Co(dmpdacn-C)(OH2)]2+ complex.

dc.contributor.authorZhou, Xiangting
dc.contributor.authorDay, Anthony
dc.contributor.authorEdwards, Alison
dc.contributor.authorWillis, Anthony
dc.contributor.authorJackson, William Gregory
dc.date.accessioned2015-12-13T22:55:16Z
dc.identifier.issn0020-1669
dc.identifier.urihttp://hdl.handle.net/1885/82456
dc.description.abstractThe 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) ligand with a N4C donor set deprotonates at a CH2 γ to an amine under extraordinarily mild conditions (pH 7) and binds as a pentadentate ligand to Co(III) as the [Co(dmpdacn-C)(OH2)]2+ complex.
dc.publisherAmerican Chemical Society
dc.sourceInorganic Chemistry
dc.subjectKeywords: 1,4 bis(2 pyridylmethyl) 1,4 diazacyclononane; amine; chloride; cobalt complex; ligand; pyridine derivative; unclassified drug; article; chemical bond; drug hydroxylation; hydrolysis kinetics; nuclear magnetic resonance; oxidation; synthesis; X ray crysta
dc.titleFacile C-H bond activation: synthesis of the N 4 C donor set pentadentate ligand 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) and a structural study of its alkyl?cobalt(III) complex [Co(dmpdacn- C )(OH 2 )](ClO 4 ) 2 ⋅H 2 O and its hydroxylated derivative [Co(dmpdacnOH- O )Cl](ClO 4 ) 2 ⋅C 3 H 6 O
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume44
dc.date.issued2005
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor030606 - Structural Chemistry and Spectroscopy
local.identifier.ariespublicationMigratedxPub10707
local.type.statusPublished Version
local.contributor.affiliationZhou, Xiangting, University of New South Wales
local.contributor.affiliationDay, Anthony, University of New South Wales
local.contributor.affiliationEdwards, Alison, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationJackson, William Gregory, University of New South Wales, ADFA
local.description.embargo2037-12-31
local.bibliographicCitation.issue2
local.bibliographicCitation.startpage452
local.bibliographicCitation.lastpage460
local.identifier.doi10.1021/ic040081q
dc.date.updated2015-12-11T11:09:25Z
local.identifier.scopusID2-s2.0-12344272889
CollectionsANU Research Publications

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