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Bis(acetylacetonato)ruthenium(II) complexes containing bulky tertiary phosphines. Formation and redox behaviour of Ru(acac) 2 (PR 3 ) (R = i Pr, Cy) complexes with ethene, carbon monoxide, and bridging dinitrogen

Bennett, Martin; Byrnes, Matthew; Chung, Guandolina; Edwards, Alison; Willis, Anthony


Reaction of cis-[Ru(acac)2(η2-C8H 14)2] (1) (acac = acetylacetonato) with two equivalents of PiPr3 in THF at -25°C gives trans-[Ru(acac) 2(PiPr3)2], trans-3, which rapidly isomerizes to cis-3 at room temperature. The poorly soluble complex [Ru(acac)2(PC

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
Source: Inorganica Chimica Acta
DOI: 10.1016/j.ica.2004.07.062


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