S-Alkylation-induced redox reactions leading to reversible sulfur�sulfur coupling in a pentamethylcyclopentadienyl ruthenium(III) thiolate-thioether system
-
Altmetric Citations
Shin, Richard; Teo, Ming; Leong, Weng Kee; Vittal, Jagadese; Yip, John; Goh, Lai Yoong; Webster, Richard
Description
Alkylation of [Cp*RuIII(tpdt)] (2) (Cp* = η5-C5Me5, tpdt = η3-S (CH2CH2S-)2) with MeI orMe3OBF4 resulted in the formation of a trans μ-η1-η1-S2 coupled species, [{Cp*RuII}2{μ-η6-(S(CH2)2S(CH2)2SMe)2}]2+ (3) as the predominant product. With MeI the
Collections | ANU Research Publications |
---|---|
Date published: | 2005 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/82426 |
Source: | Organometallics |
DOI: | 10.1021/om049081o |
Download
File | Description | Size | Format | Image |
---|---|---|---|---|
01_Shin_S-Alkylation-induced_redox_2005.pdf | 402.61 kB | Adobe PDF | Request a copy |
Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.
Updated: 17 November 2022/ Responsible Officer: University Librarian/ Page Contact: Library Systems & Web Coordinator