Skip navigation
Skip navigation

S-Alkylation-induced redox reactions leading to reversible sulfur�sulfur coupling in a pentamethylcyclopentadienyl ruthenium(III) thiolate-thioether system

Shin, Richard; Teo, Ming; Leong, Weng Kee; Vittal, Jagadese; Yip, John; Goh, Lai Yoong; Webster, Richard


Alkylation of [Cp*RuIII(tpdt)] (2) (Cp* = η5-C5Me5, tpdt = η3-S (CH2CH2S-)2) with MeI orMe3OBF4 resulted in the formation of a trans μ-η1-η1-S2 coupled species, [{Cp*RuII}2{μ-η6-(S(CH2)2S(CH2)2SMe)2}]2+ (3) as the predominant product. With MeI the

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
Source: Organometallics
DOI: 10.1021/om049081o


File Description SizeFormat Image
01_Shin_S-Alkylation-induced_redox_2005.pdf402.61 kBAdobe PDF    Request a copy

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  19 May 2020/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator