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S-Alkylation-induced redox reactions leading to reversible sulfur�sulfur coupling in a pentamethylcyclopentadienyl ruthenium(III) thiolate-thioether system

Shin, Richard; Teo, Ming; Leong, Weng Kee; Vittal, Jagadese; Yip, John; Goh, Lai Yoong; Webster, Richard

Description

Alkylation of [Cp*RuIII(tpdt)] (2) (Cp* = η5-C5Me5, tpdt = η3-S (CH2CH2S-)2) with MeI orMe3OBF4 resulted in the formation of a trans μ-η1-η1-S2 coupled species, [{Cp*RuII}2{μ-η6-(S(CH2)2S(CH2)2SMe)2}]2+ (3) as the predominant product. With MeI the

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/82426
Source: Organometallics
DOI: 10.1021/om049081o

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