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Formation of metallaboratranes: the missing link. The first iridaboratranes, [IrH(CO)(PPh 3 ){ κ 3 - B,S,S -B(mt) 2 R}]( Ir→B ) (mt = methimazolyl, R = mt, H)

Crossley, Ian R; Hill, Anthony; Willis, Anthony


The reaction of Vaska's complex with 1 equiv of Na[HB(mt)3] or Na[H2(mt)2] (mt = methimazolyl) affords the iridaboratranes [IrH(CO)(PPh3){k3-B,S,S′-B(mt) 2R}](IrI→B) (R = mt, H), the first examples of metallaboratranes in which the transannular metal-

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
Source: Organometallics
DOI: 10.1021/om040128f


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