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Reactivity of cyclooligophosphanes: synthesis and structural characterisation of cyclo -1,4-(BH 3 ) 2 (P 4 Ph 4 CH 2 ) and cyclo -1,2-(BH 3 ) 2 (P 5 Ph 5 )

Wolf, Robert; Finger, Markus; Limburg, Carolin; Willis, Anthony; Wild, Stanley (Bruce); Hey-Hawkins, Evamarie

Description

The borane complexes cyclo-1,4-(BH3)2(P 4Ph4CH2) (3) and cyclo-1,2-(BH 3)2(P5Ph5) (4) were prepared by reaction of cyclo-(P4Ph4CH2) and cyclo-(P 5Ph5) with BH3(SMe2). Only the 2: 1 complexes 3 and 4 were isolated, even when an excess of the borane source

dc.contributor.authorWolf, Robert
dc.contributor.authorFinger, Markus
dc.contributor.authorLimburg, Carolin
dc.contributor.authorWillis, Anthony
dc.contributor.authorWild, Stanley (Bruce)
dc.contributor.authorHey-Hawkins, Evamarie
dc.date.accessioned2015-12-13T22:54:05Z
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/82082
dc.description.abstractThe borane complexes cyclo-1,4-(BH3)2(P 4Ph4CH2) (3) and cyclo-1,2-(BH 3)2(P5Ph5) (4) were prepared by reaction of cyclo-(P4Ph4CH2) and cyclo-(P 5Ph5) with BH3(SMe2). Only the 2: 1 complexes 3 and 4 were isolated, even when an excess of the borane source
dc.publisherRoyal Society of Chemistry
dc.sourceDalton Transactions
dc.subjectKeywords: Boron; Carbon; Hydrogen; Isomers; Mixtures; Nuclear magnetic resonance spectroscopy; Synthesis (chemical); X ray analysis; Borane complexes; Cyclooligophosphanes; Diastereomers; Lithium salt; Stereoisomer; Organic compounds; borane derivative; cation; pho
dc.titleReactivity of cyclooligophosphanes: synthesis and structural characterisation of cyclo -1,4-(BH 3 ) 2 (P 4 Ph 4 CH 2 ) and cyclo -1,2-(BH 3 ) 2 (P 5 Ph 5 )
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume2006
dc.date.issued2006
local.identifier.absfor030204 - Main Group Metal Chemistry
local.identifier.ariespublicationMigratedxPub10377
local.type.statusPublished Version
local.contributor.affiliationWolf, Robert, University of Leipzig
local.contributor.affiliationFinger, Markus, Wilhelm-Ostwald-Institut fur Physikalische und Theoretische Chemie
local.contributor.affiliationLimburg, Carolin, University of Leipzig
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWild, Stanley (Bruce), College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHey-Hawkins, Evamarie, University of Leipzig
local.description.embargo2037-12-31
local.bibliographicCitation.issue6
local.bibliographicCitation.startpage831
local.bibliographicCitation.lastpage837
local.identifier.doi10.1039/b511833f
dc.date.updated2015-12-11T11:01:37Z
local.identifier.scopusID2-s2.0-33645503732
CollectionsANU Research Publications

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