Practical synthesis and Diels-Alder chemistry of [4]dendralene
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Payne, Alan; Willis, Anthony; Sherburn, Michael
Description
Spectacular new atom efficient domino cycloaddition sequences involving [4]dendralene, the simplest cross-conjugated tetraene, are reported. Up to eight stereocenters, three new rings, and six C-C bonds are generated in one synthetic operation. The site selectivity of dienophile addition to cross-conjugated trienes and tetraenes is controlled with a simple Lewis acid.
| Collections | ANU Research Publications |
|---|---|
| Date published: | 2005 |
| Type: | Journal article |
| URI: | http://hdl.handle.net/1885/82035 |
| Source: | Journal of the American Chemical Society |
| DOI: | 10.1021/ja053772+ |
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| File | Description | Size | Format | Image |
|---|---|---|---|---|
| 01_Payne_Practical_synthesis_and_2005.pdf | 123.25 kB | Adobe PDF | Request a copy |
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