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Redox-dependent isomerization of organometallic Ru II /Ru III compounds containing the hydrotris(methimazolyl)borate ligand: an electrochemical square scheme mechanism

Kuan, Seah Ling; Leong, Weng Kee; Goh, Lai Yoong; Webster, Richard


[Cp*RuIII{HB(mt)3}]X (1A(X); X = Cl, PF 6) and [Cp*RuII{HB(mt)3}] (2A) (Cp* = η5-C5-Me5, mt = N-methyl-2- mercaptoimidazol-1-yl) were synthesized by the reactions of K[HB(mt) 3] with [Cp*RuIIICl2]2 and [Cp*RuII(OMe)]2, respectively. 1A and 2A exist in th

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
Source: Organometallics
DOI: 10.1021/om050432o


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