Skip navigation
Skip navigation

Aminocyclodextrins to facilitate the deprotonation of 4- tert -butyl-α-nitrotoluene

Request a Copy

link to publisher version

  • Altmetric Citations

Barr, Lorna; Easton, Christopher; Lee, Kitty; Lincoln, Stephen F

Description

6A-Amino-6A-deoxy-β-cyclodextrin enhances the rate of the deprotonation of 4-terf-butyl-α-nitrotoluene. The rate constants for reaction of the cyclodextrin-bound species, kinc = 4 × 10-3, 9 × 10-3 and 19 × 10 -3 s-1, at pH 6.0, 6.5 and 7.0, respectiv

dc.contributor.authorBarr, Lorna
dc.contributor.authorEaston, Christopher
dc.contributor.authorLee, Kitty
dc.contributor.authorLincoln, Stephen F
dc.date.accessioned2015-12-13T22:53:50Z
dc.identifier.issn1477-0520
dc.identifier.urihttp://hdl.handle.net/1885/81990
dc.description.abstract6A-Amino-6A-deoxy-β-cyclodextrin enhances the rate of the deprotonation of 4-terf-butyl-α-nitrotoluene. The rate constants for reaction of the cyclodextrin-bound species, kinc = 4 × 10-3, 9 × 10-3 and 19 × 10 -3 s-1, at pH 6.0, 6.5 and 7.0, respectiv
dc.publisherRoyal Society of Chemistry
dc.sourceOrganic and Biomolecular Chemistry
dc.subjectKeywords: Acceleration; Amines; Complexation; Deuterium; Ketones; Oligomers; pH effects; Toluene; 4-terf-butyl-?-nitrotoluene; Aminocyclodextrins; Hydrogen-deuterium exchange; Rate acceleration; Reaction kinetics; cyclodextrin; drug derivative; toluene; article; ch
dc.titleAminocyclodextrins to facilitate the deprotonation of 4- tert -butyl-α-nitrotoluene
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume3
dc.date.issued2005
local.identifier.absfor030302 - Nanochemistry and Supramolecular Chemistry
local.identifier.ariespublicationMigratedxPub10292
local.type.statusPublished Version
local.contributor.affiliationBarr, Lorna, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationEaston, Christopher, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLee, Kitty, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLincoln, Stephen F, University of Adelaide
local.description.embargo2037-12-31
local.bibliographicCitation.issue16
local.bibliographicCitation.startpage2990
local.bibliographicCitation.lastpage2993
local.identifier.doi10.1039/b506187c
dc.date.updated2015-12-11T11:00:07Z
local.identifier.scopusID2-s2.0-24144454152
CollectionsANU Research Publications

Download

File Description SizeFormat Image
01_Barr_Aminocyclodextrins_to_2005.pdf126.4 kBAdobe PDF    Request a copy
Show simple item record


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  17 November 2022/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator