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Intramolecular Diels-Alder reactions of ester-linked 1,3,8-nonatrienes

Cayzer, Tory; Paddon-Row, Michael; Moran, Damian; Payne, Alan; Turner, Peter; Sherburn, Michael

Description

Penta-1,3-dienyl acrylates undergo kinetically controlled intramolecular Diels-Alder (IMDA) reactions and DFT calculations (B3LYP/6-31+G(d)) predict stereoselectivities that are in very good agreement with the experimental values. The nature of the diene

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/81699
Source: Journal of Organic Chemistry
DOI: 10.1021/jo0505829

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