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A universally applicable composite modulated structure approach to ordered BaxMyTi8−yO16 hollandite-type solid solutions

Carter, Melody; Withers, Raymond

Description

A wide range of barium titanate hollandites of the form Bax2+Mx2+Ti8-x4+O16 (M=Zn, Co, Mg, Fe and Mn) and Bax2+M2x3+Ti8-2x4+O16 (M=Fe) with nominal x ranging from 1.0 to 1.4 have been synthesized and examined to investigate the solid solution range and the nature of the ordering of the Ba ions. Electron diffraction studies confirm that the barium titanate hollandites are composite modulated single phase solid solutions made up of mutually incommensurable (along b) framework and Ba ion...[Show more]

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/81688
Source: Journal of Solid State Chemistry
DOI: 10.1016/j.jssc.2005.03.040

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