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Stoichiometric and catalytic demercuration of bis(tricarbido)mercurials: The first dimetallaoctatetraynes

Dewhurst, Rian; Hill, Anthony; Willis, Anthony

Description

Treating the complexes [Hg{C≡CC≡W-(CO)2L} 2] (L = HB(pz)3 (1a), HB(pz′)3 (1b);pz = pyrazol-1-yl; pz′ = 3,5-dimethylpyrazol-1-yl) with 1 equiv of cis-[PtCl2(PPh3)2] or a catalytic amount of trans-[RhCl(CO)-(PPh3)2] provides the bimetallic complexes

dc.contributor.authorDewhurst, Rian
dc.contributor.authorHill, Anthony
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-13T22:52:30Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/81606
dc.description.abstractTreating the complexes [Hg{C≡CC≡W-(CO)2L} 2] (L = HB(pz)3 (1a), HB(pz′)3 (1b);pz = pyrazol-1-yl; pz′ = 3,5-dimethylpyrazol-1-yl) with 1 equiv of cis-[PtCl2(PPh3)2] or a catalytic amount of trans-[RhCl(CO)-(PPh3)2] provides the bimetallic complexes
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Alcohols; Catalysis; Chemical bonds; Crystal structure; Molecular structure; Nuclear magnetic resonance; Stoichiometry; Synthesis (chemical); Transition metals; Bis(tricarbido)mercurials; Catalytic demercuration; Dimetallaoctatetraynes; Ligands; Mercury c
dc.titleStoichiometric and catalytic demercuration of bis(tricarbido)mercurials: The first dimetallaoctatetraynes
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume24
dc.date.issued2005
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub9890
local.type.statusPublished Version
local.contributor.affiliationDewhurst, Rian, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue13
local.bibliographicCitation.startpage3043
local.bibliographicCitation.lastpage3046
local.identifier.doi10.1021/om058011u
dc.date.updated2015-12-11T10:51:23Z
local.identifier.scopusID2-s2.0-23144450389
CollectionsANU Research Publications

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