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Stoichiometric and catalytic demercuration of bis(tricarbido)mercurials: The first dimetallaoctatetraynes

Dewhurst, Rian; Hill, Anthony; Willis, Anthony


Treating the complexes [Hg{C≡CC≡W-(CO)2L} 2] (L = HB(pz)3 (1a), HB(pz′)3 (1b);pz = pyrazol-1-yl; pz′ = 3,5-dimethylpyrazol-1-yl) with 1 equiv of cis-[PtCl2(PPh3)2] or a catalytic amount of trans-[RhCl(CO)-(PPh3)2] provides the bimetallic complexes

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
Source: Organometallics
DOI: 10.1021/om058011u


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