Skip navigation
Skip navigation
A change is coming. Click to see a sneak peek of the new Open Research Repository.

Thiocarbamoyl complexes of ruthenium(II), rhodium(III), and iridium(III)

Request a Copy

link to publisher version

  • Altmetric Citations

Hill, Anthony; Tocher, Derek; White, Andrew G; Williams, David; Wilton-Ely, James

Description

The reaction of [Ru(CO)2(PPh3)3] (1) or [Ru(η2-CS2)(CO)2(PPh3) 2] with N,N-dimethylthio-carbamoyl chloride provides [Ru(η2-SCNMe2)(CO)2(PPh2) 2]Cl (2·C1), thermolysis of which yields [Ru(η 2-SCNMe2)Cl(CO)(PPh2)2] (3). Treatment of 2·C1 with NaBH4 lea

dc.contributor.authorHill, Anthony
dc.contributor.authorTocher, Derek
dc.contributor.authorWhite, Andrew G
dc.contributor.authorWilliams, David
dc.contributor.authorWilton-Ely, James
dc.date.accessioned2015-12-13T22:51:58Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/81334
dc.description.abstractThe reaction of [Ru(CO)2(PPh3)3] (1) or [Ru(η2-CS2)(CO)2(PPh3) 2] with N,N-dimethylthio-carbamoyl chloride provides [Ru(η2-SCNMe2)(CO)2(PPh2) 2]Cl (2·C1), thermolysis of which yields [Ru(η 2-SCNMe2)Cl(CO)(PPh2)2] (3). Treatment of 2·C1 with NaBH4 lea
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Chemical analysis; Complexation; Hydrochloric acid; Iridium; Isomers; Photolysis; Rhodium; Ruthenium; Substitution reactions; Metallacyclic complexes; Thermolysis; Organometallics
dc.titleThiocarbamoyl complexes of ruthenium(II), rhodium(III), and iridium(III)
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume24
dc.date.issued2005
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub9649
local.type.statusPublished Version
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationTocher, Derek, University College London
local.contributor.affiliationWhite, Andrew G, University of Queensland
local.contributor.affiliationWilliams, David, Imperial College London
local.contributor.affiliationWilton-Ely, James, University College London
local.description.embargo2037-12-31
local.bibliographicCitation.issue22
local.bibliographicCitation.startpage5342
local.bibliographicCitation.lastpage5355
local.identifier.doi10.1021/om050514c
dc.date.updated2015-12-11T10:48:11Z
local.identifier.scopusID2-s2.0-27544474630
CollectionsANU Research Publications

Download

File Description SizeFormat Image
01_Hill_Thiocarbamoyl_complexes_of_2005.pdf318.59 kBAdobe PDF    Request a copy
Show simple item record


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  17 November 2022/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator