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Thiocarbamoyl complexes of ruthenium(II), rhodium(III), and iridium(III)

Hill, Anthony; Tocher, Derek; White, Andrew G; Williams, David; Wilton-Ely, James


The reaction of [Ru(CO)2(PPh3)3] (1) or [Ru(η2-CS2)(CO)2(PPh3) 2] with N,N-dimethylthio-carbamoyl chloride provides [Ru(η2-SCNMe2)(CO)2(PPh2) 2]Cl (2·C1), thermolysis of which yields [Ru(η 2-SCNMe2)Cl(CO)(PPh2)2] (3). Treatment of 2·C1 with NaBH4 lea

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
Source: Organometallics
DOI: 10.1021/om050514c


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