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Hydrothermal synthesis of chiral metal(II) phosphinates derived from camphor

Beckmann, Jens; Duthie, Andrew; Ruttinger, Roman; Schwich, Torsten

Description

The diastereoselective synthesis of bis(3-endo-camphoryl)phosphinic acid (1) and its 2-bornen-2-yl ester 2 from the reaction of lithium camphor enolate with phosphorus trichloride and the hydrothermal synthesis of three chiral molecular metal(II) phosphinates of the type M(O2PR2) 2.2R2P(O)OH [M = Co (3); Ni (4); Pb (5); R = 3-endo-camphoryl] from the reaction of 1 with metal(II) acetates or nitrates is described. The molecular structures of 1-5 are reported.

dc.contributor.authorBeckmann, Jens
dc.contributor.authorDuthie, Andrew
dc.contributor.authorRuttinger, Roman
dc.contributor.authorSchwich, Torsten
dc.date.accessioned2015-12-13T22:48:27Z
dc.identifier.issn0044-2313
dc.identifier.urihttp://hdl.handle.net/1885/80107
dc.description.abstractThe diastereoselective synthesis of bis(3-endo-camphoryl)phosphinic acid (1) and its 2-bornen-2-yl ester 2 from the reaction of lithium camphor enolate with phosphorus trichloride and the hydrothermal synthesis of three chiral molecular metal(II) phosphinates of the type M(O2PR2) 2.2R2P(O)OH [M = Co (3); Ni (4); Pb (5); R = 3-endo-camphoryl] from the reaction of 1 with metal(II) acetates or nitrates is described. The molecular structures of 1-5 are reported.
dc.publisherWalter de Gruyter
dc.sourceZeitschrift fuer Anorganische und Allgemeine Chemie
dc.subjectKeywords: Chirality; Hydrothermal synthesis; Phosphinate ligands; Terpenoids
dc.titleHydrothermal synthesis of chiral metal(II) phosphinates derived from camphor
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume635
dc.date.issued2009
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationf5625xPUB8430
local.type.statusPublished Version
local.contributor.affiliationBeckmann, Jens, Freie Universitat Berlin
local.contributor.affiliationDuthie, Andrew, Deakin University
local.contributor.affiliationRuttinger, Roman, Freie Universitat Berlin
local.contributor.affiliationSchwich, Torsten, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue9-10
local.bibliographicCitation.startpage1412
local.bibliographicCitation.lastpage1419
local.identifier.doi10.1002/zaac.200900065
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T09:41:56Z
local.identifier.scopusID2-s2.0-69249136145
local.identifier.thomsonID000269281600024
CollectionsANU Research Publications

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