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Hydrothermal synthesis of chiral metal(II) phosphinates derived from camphor

Beckmann, Jens; Duthie, Andrew; Ruttinger, Roman; Schwich, Torsten

Description

The diastereoselective synthesis of bis(3-endo-camphoryl)phosphinic acid (1) and its 2-bornen-2-yl ester 2 from the reaction of lithium camphor enolate with phosphorus trichloride and the hydrothermal synthesis of three chiral molecular metal(II) phosphinates of the type M(O2PR2) 2.2R2P(O)OH [M = Co (3); Ni (4); Pb (5); R = 3-endo-camphoryl] from the reaction of 1 with metal(II) acetates or nitrates is described. The molecular structures of 1-5 are reported.

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
URI: http://hdl.handle.net/1885/80107
Source: Zeitschrift fuer Anorganische und Allgemeine Chemie
DOI: 10.1002/zaac.200900065

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