Should dithiophosphinate esters function as RAFT agents?
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Hodgson, Jennifer; Green, Katy; Coote, Michelle
Description
(Chemical Equation Presented) High-level ab initio calculations indicate that•CH3 addition to the sulfur center of S=P(Z)(Z′)SCH3 (Z,Z′ = CH3, CN, OCH3, Ph) is considerably less exothermic than addition to the corresponding RAFT agents, S=C(Z)SCH3.
Collections | ANU Research Publications |
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Date published: | 2005 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/79907 |
Source: | Organic Letters |
DOI: | 10.1021/ol0516420 |
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01_Hodgson_Should_dithiophosphinate_2005.pdf | 68.31 kB | Adobe PDF | Request a copy |
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