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Should dithiophosphinate esters function as RAFT agents?

Hodgson, Jennifer; Green, Katy; Coote, Michelle

Description

(Chemical Equation Presented) High-level ab initio calculations indicate that•CH3 addition to the sulfur center of S=P(Z)(Z′)SCH3 (Z,Z′ = CH3, CN, OCH3, Ph) is considerably less exothermic than addition to the corresponding RAFT agents, S=C(Z)SCH3.

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/79907
Source: Organic Letters
DOI: 10.1021/ol0516420

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