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Neutral and anionic tricarbido complexes of gold(I)

Dewhurst, Rian; Hill, Anthony; Smith, Matthew


Desilylation of [W(≡CC≡CSiMe3)(CO)2L] (L = HB(pz)3, HB(pz′)3; pz = pyrazol-1-yl, pz′ =3,5-dimethylpyrazol-l-yl) with [Bu4N]F in the presence of [AuCl(PPh3)] provides the neutral complexes [W(≡CC≡ CAuPPh3)(CO)2L] in addition to traces of the sa

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
Source: Organometallics
DOI: 10.1021/om050528i


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