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Enantioselective total syntheses of the alkaloids (−)-rhazinal, (−)-rhazinilam, (−)-leuconolam and (+)- epi -leuconolam

Banwell, Martin; Beck, Daniel; Willis, Anthony


The title alkaloids, (-)-1, (-)-2, (-)-4 and (+)-5 respectively, have each been prepared from the enantiomerically enriched (74% ee) tetrahydroindolizine 14 which is itself obtained via an organocatalyzed and enantioselective intramolecular Michael addition reaction of the pyrrole 13 incorporating an N-tethered and β,β-disubstituted acrylaldehyde moiety.

CollectionsANU Research Publications
Date published: 2006
Type: Journal article


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