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The exciton contribution to the Faraday B term MCD of molecular dimers

Hughes, Joseph; Pace, Ronald; Krausz, Elmars

Description

Absorption properties of aggregated molecular systems, which are not necessarily chemically bonded, can be analysed in terms of exciton phenomena. Angular momentum terms arising from exciton coupling often dominate the natural circular dichroism (CD) of molecular aggregates. This Letter, for the first time, extends such an analysis to the magnetic circular dichroism (MCD) of exciton-coupled molecular dimers. In particular, we determine the contribution to the Faraday B term MCD of an arbitrary...[Show more]

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
URI: http://hdl.handle.net/1885/79666
Source: Chemical Physics Letters
DOI: 10.1016/j.cplett.2003.12.067

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