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Time-Dependent Changes in the Formation of Titania-Based Films at the Air-Water Interface

Henderson, Mark; King, David; White, John


The growth of surfactant-assisted titanium dioxide-based films at the air-water interface previously reported (Henderson et al. Aust. J. Chem. 2003, 56, 933) has been monitored with a time resolution of minutes over the whole growth period by X-ray energy-dispersive reflectometry. Two new phenomena are described: (a) short-term shifts in the Bragg spacing of the layer structure and (b) the periodic disappearance of the diffraction from the film. We associate these with changes in the chemistry...[Show more]

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: Langmuir
DOI: 10.1021/la0303299


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