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Mixed-metal cluster chemistry. 26. Proclivity for "all-terminal" or "plane-of-bridging-carbonyls" ligand disposition in tungsten-triiridium clusters

Usher, Alistair; Dalton, Gulliver; Lucas, Nigel; Waterman, Susan; Petrie, Simon; Stranger, Robert; Willis, Anthony; Humphrey, Mark

Description

Reaction of WH(CO)3(η-C5Me5) with IrCl(CO)2(4-H2NC6H4Me) affords WIr3(μ-CO)3(CO)8 (η-C5Me5) in low yield. A structural study reveals a WIr2-centred plane of bridging carbonyls, in contrast to the crystal structure of WIr3(CO)11 (η-C5H5) (all-terminal

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
URI: http://hdl.handle.net/1885/79513
Source: Journal of Organometallic Chemistry
DOI: 10.1016/j.jorganchem.2003.09.026

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