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Water oxidation in PS11-H atom abstraction revisited

Pace, Ronald; Ahrling, Karin

Description

A model for the water oxidation reaction in Photosystem II (PSII) is presented, based on an H atom abstraction mechanism. The model rationalises the S-state dependence of observed substrate water exchange kinetics [Biochim. Biophys. Acta 1503 (2001) 197]

dc.contributor.authorPace, Ronald
dc.contributor.authorAhrling, Karin
dc.date.accessioned2015-12-13T22:43:50Z
dc.date.available2015-12-13T22:43:50Z
dc.identifier.issn0006-3002
dc.identifier.urihttp://hdl.handle.net/1885/79378
dc.description.abstractA model for the water oxidation reaction in Photosystem II (PSII) is presented, based on an H atom abstraction mechanism. The model rationalises the S-state dependence of observed substrate water exchange kinetics [Biochim. Biophys. Acta 1503 (2001) 197]
dc.publisherElsevier
dc.sourceBiochimica et Biophysica Acta: International journal of Biochemistry and Biophysics
dc.subjectKeywords: catalase; hydrogen; manganese; catalysis; catalyst; density; electron; kinetics; ligation; model; mutagenesis; oxidation; phase transition; photosystem II; priority journal; proton transport; review; Calcium; Catalytic Domain; Electron Spin Resonance Spec EPR; EXAFS; Extended X-ray absorption fine structure; H atom abstraction; MeOH; Methanol; Mn cluster; Photosystem II; PSII; Water oxidising complex; WOC; X-ray absorption near edge spectroscopy; XANES
dc.titleWater oxidation in PS11-H atom abstraction revisited
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume1655
dc.date.issued2004
local.identifier.absfor030699 - Physical Chemistry not elsewhere classified
local.identifier.ariespublicationMigratedxPub7832
local.type.statusPublished Version
local.contributor.affiliationPace, Ronald, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationAhrling, Karin, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.startpage172
local.bibliographicCitation.lastpage178
local.identifier.doi10.1016/j.bbabio.2003.09.016
dc.date.updated2015-12-11T10:14:27Z
local.identifier.scopusID2-s2.0-1942472548
CollectionsANU Research Publications

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