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Non-linear Optical Properties of Transition Metal Acetylides and Their Derivatives

Powell, Clem; Humphrey, Mark

Description

The nonlinear optical (NLO) properties of metal acetylide and vinylidene complexes are summarized, and molecular structure-NLO property trends are developed. The origin of NLO effects in molecules is presented, and the advantages and shortcomings of experimental procedures that have been used to measure optical nonlinearities for these complexes are discussed. Attempts to "switch" optical nonlinearities of acetylide or vinylidene complexes are summarized.

dc.contributor.authorPowell, Clem
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-13T22:43:07Z
dc.date.available2015-12-13T22:43:07Z
dc.identifier.issn0010-8545
dc.identifier.urihttp://hdl.handle.net/1885/79057
dc.description.abstractThe nonlinear optical (NLO) properties of metal acetylide and vinylidene complexes are summarized, and molecular structure-NLO property trends are developed. The origin of NLO effects in molecules is presented, and the advantages and shortcomings of experimental procedures that have been used to measure optical nonlinearities for these complexes are discussed. Attempts to "switch" optical nonlinearities of acetylide or vinylidene complexes are summarized.
dc.publisherElsevier
dc.sourceCoordination Chemistry Reviews
dc.subjectKeywords: acetic acid derivative; transition element; vinyl derivative; calculation; chemical structure; complex formation; electric field; nonlinear system; optics; review; structure analysis; theoretical study Acetylide complexes; Alkynyl complexes; Cubic nonlinearities; Hyperpolarizabilities; Nonlinear optics; Quadratic nonlinearities; Vinylidene complexes
dc.titleNon-linear Optical Properties of Transition Metal Acetylides and Their Derivatives
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume248
dc.date.issued2004
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub7591
local.type.statusPublished Version
local.contributor.affiliationPowell, Clem, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.startpage725
local.bibliographicCitation.lastpage756
local.identifier.doi10.1016/j.ccr.2004.03.009
dc.date.updated2015-12-11T10:10:44Z
local.identifier.scopusID2-s2.0-2942574623
CollectionsANU Research Publications

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