Ring fragmentation processes resulting from acid catalysed diazo ketone cyclisations
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Hutt, Oliver; Mander, Lewis; Willis, Anthony
Description
The initial products from the cyclisation of hexahydrophenanthryl diazo ketones with participation by either the alkene bonds or the aromatic ring (Ar1,4) undergo rearrangement by 1,2 bond shifts or unexpected bond fission. Benzocyclo-octanyl ketones were formed from the latter process.
dc.contributor.author | Hutt, Oliver | |
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dc.contributor.author | Mander, Lewis | |
dc.contributor.author | Willis, Anthony | |
dc.date.accessioned | 2015-12-13T22:42:11Z | |
dc.identifier.issn | 0040-4039 | |
dc.identifier.uri | http://hdl.handle.net/1885/78852 | |
dc.description.abstract | The initial products from the cyclisation of hexahydrophenanthryl diazo ketones with participation by either the alkene bonds or the aromatic ring (Ar1,4) undergo rearrangement by 1,2 bond shifts or unexpected bond fission. Benzocyclo-octanyl ketones were formed from the latter process. | |
dc.publisher | Elsevier | |
dc.source | Tetrahedron Letters | |
dc.subject | Keywords: alkene; ketone derivative; article; catalysis; catalyst; cyclization; fragmentation reaction; reaction analysis Benzocyclo-octanones; Cyclisation; Diazo ketone; Ring fragmentation | |
dc.title | Ring fragmentation processes resulting from acid catalysed diazo ketone cyclisations | |
dc.type | Journal article | |
local.description.notes | Imported from ARIES | |
local.description.refereed | Yes | |
local.identifier.citationvolume | 46 | |
dc.date.issued | 2005 | |
local.identifier.absfor | 030503 - Organic Chemical Synthesis | |
local.identifier.ariespublication | MigratedxPub7414 | |
local.type.status | Published Version | |
local.contributor.affiliation | Hutt, Oliver, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Mander, Lewis, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Willis, Anthony, College of Physical and Mathematical Sciences, ANU | |
local.description.embargo | 2037-12-31 | |
local.bibliographicCitation.issue | 27 | |
local.bibliographicCitation.startpage | 4569 | |
local.bibliographicCitation.lastpage | 4572 | |
local.identifier.doi | 10.1016/j.tetlet.2005.05.009 | |
dc.date.updated | 2015-12-11T10:06:02Z | |
local.identifier.scopusID | 2-s2.0-20344408498 | |
Collections | ANU Research Publications |
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