Skip navigation
Skip navigation

Ring fragmentation processes resulting from acid catalysed diazo ketone cyclisations

Hutt, Oliver; Mander, Lewis; Willis, Anthony

Description

The initial products from the cyclisation of hexahydrophenanthryl diazo ketones with participation by either the alkene bonds or the aromatic ring (Ar1,4) undergo rearrangement by 1,2 bond shifts or unexpected bond fission. Benzocyclo-octanyl ketones were formed from the latter process.

dc.contributor.authorHutt, Oliver
dc.contributor.authorMander, Lewis
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-13T22:42:11Z
dc.identifier.issn0040-4039
dc.identifier.urihttp://hdl.handle.net/1885/78852
dc.description.abstractThe initial products from the cyclisation of hexahydrophenanthryl diazo ketones with participation by either the alkene bonds or the aromatic ring (Ar1,4) undergo rearrangement by 1,2 bond shifts or unexpected bond fission. Benzocyclo-octanyl ketones were formed from the latter process.
dc.publisherElsevier
dc.sourceTetrahedron Letters
dc.subjectKeywords: alkene; ketone derivative; article; catalysis; catalyst; cyclization; fragmentation reaction; reaction analysis Benzocyclo-octanones; Cyclisation; Diazo ketone; Ring fragmentation
dc.titleRing fragmentation processes resulting from acid catalysed diazo ketone cyclisations
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume46
dc.date.issued2005
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationMigratedxPub7414
local.type.statusPublished Version
local.contributor.affiliationHutt, Oliver, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMander, Lewis, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue27
local.bibliographicCitation.startpage4569
local.bibliographicCitation.lastpage4572
local.identifier.doi10.1016/j.tetlet.2005.05.009
dc.date.updated2015-12-11T10:06:02Z
local.identifier.scopusID2-s2.0-20344408498
CollectionsANU Research Publications

Download

File Description SizeFormat Image
01_Hutt_Ring_fragmentation_processes_2005.pdf155.27 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  17 November 2022/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator