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Ring fragmentation processes resulting from acid catalysed diazo ketone cyclisations

Hutt, Oliver; Mander, Lewis; Willis, Anthony


The initial products from the cyclisation of hexahydrophenanthryl diazo ketones with participation by either the alkene bonds or the aromatic ring (Ar1,4) undergo rearrangement by 1,2 bond shifts or unexpected bond fission. Benzocyclo-octanyl ketones were formed from the latter process.

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
Source: Tetrahedron Letters
DOI: 10.1016/j.tetlet.2005.05.009


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