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Computer-aided design of a destabilized RAFT adduct radical: Toward improved RAFT agents for styrene- block -vinyl acetate copolymers

Coote, Michelle; Henry, David

Description

High-level ab initio molecular orbital calculations indicate that a fluorine Z substituent significantly destabilizes the RAFT adduct radical, R'SO·(Z)SR, relative to known Z substituents. This destabilization of the RAFT adduct radical lowers the fragme

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/78835
Source: Macromolecules
DOI: 10.1021/ma050415a

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