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Tandem mass spectrometry study of protonated methanol�water aggregates

Jackson, Phillip


Protonated nanodroplets containing methanol (M) and water (W) solvent monomers (up to M23W41H+) have been generated using electrospray ionisation (ESI) in conjunction with both high-solvent and low-drying gas-flow rates in a triple quadrupole mass spectrometer. Under the conditions employed, pure methanol clusters (MmH+) dominate the low-mass region of the spectrum (m<7). When the number of methanol monomers exceeds seven, a rapid increase in the addition of water to the clusters was observed,...[Show more]

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: International Journal of Mass Spectrometry
DOI: 10.1016/j.ijms.2003.11.007


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