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Polyazolyl chelate chemistry. 13. An osmaboratrane

Foreman, Mark; Hill, Anthony; White, Andrew G; Williams, David


The reaction of [Os(C6H5)Cl(CO)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) results in benzene elimination and the formation of the first osmaboratrane [B(mt)3Os(CO)(PPh3)](Os→B), the crystal structure of which reveals a somewhat long transannular dati

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: Organometallics
DOI: 10.1021/om0306123


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