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Caveats for poly(methimazolyl)borate chemistry: the novel inorganic heterocycles [H 2 C(mt) 2 BR 2 ]Cl (mt = methimazolyl; BR 2 = BH 2 , BH(mt), 9�BBN)

Crossley, Ian R; Hill, Anthony; Humphrey, Elizabeth; Smith, Matthew; Tshabang, Never; Willis, Anthony


Whilst frequently used for reactions of poly(methimazolyl)borates, dichloromethane is not an innocent solvent, but rather slowly forms heterocyclic salts [H2C(mt)2BR2]Cl, three examples of which (BR2 = BH2, BH(mt), 9-borabicyclononyl) have been structurally characterised to confirm the unprecedented B(NCS)2C connectivity.

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: Chemical Communications
DOI: 10.1039/b407733d


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