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A combined temperature-dependent electron and single crystal X-ray diffraction study of the fresnoite compound Rb2V4+V25+O8

Withers, Raymond; Hoche, Thomas; Liu, Yun; Esmaeilzadeh, Saeid; Keding, Ralf; Sales, Brian


High-purity Rb2V3O8 has been grown and temperature-dependent electron and single-crystal X-ray diffraction used to carefully investigate its fresnoite-type reciprocal lattice. In contrast to other recently investigated representatives of the fresnoite family of compounds, Rb2V3O8 is not incommensurately modulated with an incommensurate basal plane primary modulation wave vector given by q∼0.3 〈110〉*. A careful low-temperature electron diffraction study has, however, revealed the existence of...[Show more]

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: Journal of Solid State Chemistry
DOI: 10.1016/j.jssc.2004.05.056


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