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Dihapto carbamoyl (carboxamide) complexes of iron(II)

Anderson, Stephen; Berridge, Timothy E; Hill, Anthony; Ng, Ying T; White, Andrew G; Williams, David

Description

The carbamoyl ferrate Li[Fe{C(=O)NiPr2}(CO)4] reacts in diethyl ether with Br2PPh3, I2PPh3, or I2 followed by triphenylphosphine to provide the complexes [Fe(η2-OCNiPr2)X-(CO)2(PPh3)] [X = I trans to PPh3 (1a); Br (1b) two isomers], each of which feature

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
URI: http://hdl.handle.net/1885/78051
Source: Organometallics
DOI: 10.1021/om0306933

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