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Reactions of tungsten alkylidynes with thionyl chloride

Anderson, Stephen; Cook, Darren J; Hill, Anthony; Malget, John; White, Andrew G; Williams, David

Description

The reaction of [W(≡CR)(CO)2(η-C5H5)] (R = C6H3Me2-2,6) with thionyl chloride provides the metallacyclic alkylidene complex [W(=CRSCRS)Cl3(η-C5H5)], while similar treatment of [W(≡CR)(CO)2{HB(pz)3}] (pz = pyrazol-1-yl) provides the alkylidyne comple

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
URI: http://hdl.handle.net/1885/78050
Source: Organometallics
DOI: 10.1021/om030691i

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