Dinitrogen activation in sterically-hindered three-coordinate transition metal complexes
Christian, Gemma; Driver, J; Stranger, Robert
Description
Dinuclear metal systems based on sterically-hindered, three-coordinate transition metal complexes of the type ML3 where the ancillary ligands L comprise bulky organic substituents, hold great promise synthetically for the activation and scission of small, multiply-bonded molecules such as N2, NO and N2O. In this study we have employed density functional methods to identify the metal/ligand combinations which achieve optimum activation and/or cleavage of N2. Strong π donor ligands such as NH2...[Show more]
Collections | ANU Research Publications |
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Date published: | 2003 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/76884 |
Source: | Faraday Discussions |
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