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Temperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)

Swiegers, Gerhard; Wild, Stanley (Bruce)

Description

The specific optical rotation of an enantiopure, syndiotactic hexa(tertiary phosphine) displays a marked temperature dependence that is consistent with the cooperative formation of helically coiled conformers in solution.

dc.contributor.authorSwiegers, Gerhard
dc.contributor.authorWild, Stanley (Bruce)
dc.date.accessioned2015-12-13T22:36:12Z
dc.identifier.issn0004-9425
dc.identifier.urihttp://hdl.handle.net/1885/76661
dc.description.abstractThe specific optical rotation of an enantiopure, syndiotactic hexa(tertiary phosphine) displays a marked temperature dependence that is consistent with the cooperative formation of helically coiled conformers in solution.
dc.publisherCSIRO Publishing
dc.sourceAustralian Journal of Chemistry
dc.subjectKeywords: Conformations; Optical rotation; Thermal effects; Conformers; Temperature dependence; Oligomers
dc.titleTemperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume58
dc.date.issued2005
local.identifier.absfor030204 - Main Group Metal Chemistry
local.identifier.ariespublicationMigratedxPub5462
local.type.statusPublished Version
local.contributor.affiliationSwiegers, Gerhard, CSIRO Molecular and Health Technologies
local.contributor.affiliationWild, Stanley (Bruce), College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue12
local.bibliographicCitation.startpage831
local.bibliographicCitation.lastpage833
local.identifier.doi10.1071/CH05253
dc.date.updated2015-12-11T09:30:31Z
local.identifier.scopusID2-s2.0-29144500359
CollectionsANU Research Publications

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