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Temperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)

Swiegers, Gerhard; Wild, Stanley (Bruce)

Description

The specific optical rotation of an enantiopure, syndiotactic hexa(tertiary phosphine) displays a marked temperature dependence that is consistent with the cooperative formation of helically coiled conformers in solution.

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/76661
Source: Australian Journal of Chemistry
DOI: 10.1071/CH05253

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