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A Bimetallic Complex Spanned by the C 4 H Ligand: Synthesis of [Cl(CO) 2 L 2 RuC≡CCH=C=RuL 2 (η-C 5 H 5 )PF 6 (L = PPh 3 )

Bartlett, Michael; Hill, Anthony; Smith, Matthew


The synthesis of the first example of a bime-tallic complex spanned by the C4H alkynylvinylidene ligand, [Cl(CO)2L 2RuC≡CCH=C-RuL2(η-C5H 5]PF6 (L = PPh3), is reported: the reaction of [Ru(CO)2L3] with butadiyne provides [RuH(C≡CC≡ CH)(CO)2L2], whic

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
Source: Organometallics
DOI: 10.1021/om050800o


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