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Cl 3 V( m -S(CH 3 ) 2 ) 3 VCl 3 2- : A First-Row, Face-Shared Bioctahedral Complex with Multiple Metal-Metal Bonding

Petrie, Simon; Stranger, Robert

Description

Density functional theory calculations have been used to investigate the structure and bonding of the d3d3 bioctahedral complexes X3V(μ-S(CH3)2)3 VX32- (X = F-, Cl-, OH-, SH-, NH2-). According to geometry optimizations using the broken-symmetry approach

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/76466
Source: Inorganic Chemistry
DOI: 10.1021/ic026276k

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