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Nitrogen and oxygen bonded (2-pyrrolidinone)-pentaamminecobalt(III): the first monodentate linkage isomers of a secondary amide

Angus, Patricia; Jackson, William Gregory

Description

The cyclic secondary amide 2-pyrrolidinone has been coordinated to the pentaamminecobalt(III) moiety to afford both O- and N-bonded linkage isomers. A deprotonated N-bonded form has also been isolated. In non-coordinating solvents the N-form rearranges to its O-bonded isomer, and in coordinating solvents some solvolysis competes with this, but much less so than for the primary amide ligand systems investigated previously. The O-bonded product ultimately loses the amide ligand completely in...[Show more]

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/76368
Source: Inorganica Chimica Acta
DOI: 10.1016/S0020-1693(02)01216-1

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