Mixed-Metal Cluster Chemistry. 21. Synthesis and Crystallographic and Electrochemical Studies of Alkyne-Coordinated Group 6-Iridium Clusters Linked by Phenylenevinylene Groups
Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters were discussed. Cyclic voltametry and ultraviolet-vis-near-infrared spectroscopy were used. Results showed that all compounds show a reversible/partially reversible oxidation which is followed by an irreversible oxidation process.
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