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Mixed-Metal Cluster Chemistry. 22. Synthesis and Crystallographic, Electrochemical, and Theoretical Studies of Alkyne-Coordinated Group 6-Iridium Clusters Linked by Phenyleneethynylene Groups

Lucas, Nigel; Notaras, Eleni; Petrie, Simon; Stranger, Robert; Humphrey, Mark

Description

Reaction between the tetrahedral cluster compound Mo2Ir2(CO)10(η5-C5 H4Me)2 (1) and 1-iodo-4-(oct-1′-ynyl)benzene afforded the pseudooctahedral cluster Mo2Ir2 {μ4-η2-Me(CH2)5 C2-4-C6 H4I}(CO)8 (η5-C5H4Me)2 (7). Similar reactions of 1 and W2Ir2(CO)10

dc.contributor.authorLucas, Nigel
dc.contributor.authorNotaras, Eleni
dc.contributor.authorPetrie, Simon
dc.contributor.authorStranger, Robert
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-13T22:34:46Z
dc.date.available2015-12-13T22:34:46Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/76273
dc.description.abstractReaction between the tetrahedral cluster compound Mo2Ir2(CO)10(η5-C5 H4Me)2 (1) and 1-iodo-4-(oct-1′-ynyl)benzene afforded the pseudooctahedral cluster Mo2Ir2 {μ4-η2-Me(CH2)5 C2-4-C6 H4I}(CO)8 (η5-C5H4Me)2 (7). Similar reactions of 1 and W2Ir2(CO)10
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Iridium clusters; Mixed metal cluster chemistry; Phenyleneethynylene groups; Crystallography; Cyclic voltammetry; Electrochemistry; Iridium compounds; Isomers; Numerical analysis; Oxidation; Probability density function; Reduction; Single crystals; Synthe
dc.titleMixed-Metal Cluster Chemistry. 22. Synthesis and Crystallographic, Electrochemical, and Theoretical Studies of Alkyne-Coordinated Group 6-Iridium Clusters Linked by Phenyleneethynylene Groups
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume22
dc.date.issued2003
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub5116
local.type.statusPublished Version
local.contributor.affiliationLucas, Nigel, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationNotaras, Eleni, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationPetrie, Simon, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationStranger, Robert, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.startpage708
local.bibliographicCitation.lastpage721
local.identifier.doi10.1021/om020910k
dc.date.updated2015-12-11T09:23:58Z
local.identifier.scopusID2-s2.0-0037450860
CollectionsANU Research Publications

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