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Mixed-Metal Cluster Chemistry. 22. Synthesis and Crystallographic, Electrochemical, and Theoretical Studies of Alkyne-Coordinated Group 6-Iridium Clusters Linked by Phenyleneethynylene Groups

Lucas, Nigel; Notaras, Eleni; Petrie, Simon; Stranger, Robert; Humphrey, Mark


Reaction between the tetrahedral cluster compound Mo2Ir2(CO)10(η5-C5 H4Me)2 (1) and 1-iodo-4-(oct-1′-ynyl)benzene afforded the pseudooctahedral cluster Mo2Ir2 {μ4-η2-Me(CH2)5 C2-4-C6 H4I}(CO)8 (η5-C5H4Me)2 (7). Similar reactions of 1 and W2Ir2(CO)10

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Organometallics
DOI: 10.1021/om020910k


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