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Effect of lone-pair stereoactivity on polyhedral volume and structural flexibility: Application to TeIVO6 octahedra

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Christy, Andrew; Mills, S J

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The Distortion Theorem implies that the irregularity of bond distances in a distorted coordination polyhedron causes an increase of mean bond distance. Examination of 40 polyhedra containing the lone-pair cation TeIV shows that this does not imply an incr

dc.contributor.authorChristy, Andrew
dc.contributor.authorMills, S J
dc.date.accessioned2015-12-13T22:30:34Z
dc.identifier.issn0108-7681
dc.identifier.urihttp://hdl.handle.net/1885/74899
dc.description.abstractThe Distortion Theorem implies that the irregularity of bond distances in a distorted coordination polyhedron causes an increase of mean bond distance. Examination of 40 polyhedra containing the lone-pair cation TeIV shows that this does not imply an incr
dc.publisherMunksgaard International Publishers
dc.rightsAuthor/s retain copyright
dc.sourceActa Crystallographica Section B: Structural Science
dc.subjectKeywords: Coordination polyhedra; Distortion theorems; Distortion theory; Lone-pair activities; Polarizable cations; Sphere surfaces; Stereoactivity; Structural flexibilities; Oxygen; Positive ions; Spheres; Geometry distortion theory; lone-pair stereoactivity; polyhedral distortion
dc.titleEffect of lone-pair stereoactivity on polyhedral volume and structural flexibility: Application to TeIVO6 octahedra
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume69
dc.date.issued2013
local.identifier.absfor040300 - GEOLOGY
local.identifier.ariespublicationf5625xPUB4363
local.type.statusPublished Version
local.contributor.affiliationChristy, Andrew, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMills, S J, Museum Victoria
local.bibliographicCitation.issue5
local.bibliographicCitation.startpage446
local.bibliographicCitation.lastpage456
local.identifier.doi10.1107/S2052519213023087
dc.date.updated2016-02-24T09:24:28Z
local.identifier.scopusID2-s2.0-84884681192
local.identifier.thomsonID000324881800004
dcterms.accessRightsOpen Access
CollectionsANU Research Publications

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