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Effect of lone-pair stereoactivity on polyhedral volume and structural flexibility: Application to TeIVO6 octahedra

Christy, Andrew; Mills, S J


The Distortion Theorem implies that the irregularity of bond distances in a distorted coordination polyhedron causes an increase of mean bond distance. Examination of 40 polyhedra containing the lone-pair cation TeIV shows that this does not imply an incr

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: Acta Crystallographica Section B: Structural Science
DOI: 10.1107/S2052519213023087
Access Rights: Open Access


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