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Organometallic complexes for nonlinear optics Part 32: Synthesis, optical spectroscopy and theoretical studies of some osmium alkynyl complexes

Morrall, Joseph; Powell, Clem; Stranger, Robert; Cifuentes, Marie; Heath, Graham; Humphrey, Mark


The complexes trans-[Os(C≡CPh)Cl(dppe)2] (1), trans-[Os(4-C≡CC6H4C≡CPh) Cl(dppe)2] (2), and 1,3,5-{trans-[OsCl(dppe)2 (4-C≡CC6H4 C≡C)]}3C6H3 (3) have been prepared. Cyclic voltammetric studies reveal a quasi-reversible oxidation process for each

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Journal of Organometallic Chemistry
DOI: 10.1016/S0022-328X(03)00039-1


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