Mechanistic insight from activation parameters for the reaction between co-enzyme B 12 and cyanide: further evidence that heterolytic Co�C bond cleavage is solvent-assisted.
Hamza, Mohamed; Cregan, Andrew; Brasch, Nicola E; van Eldik, Rudi
Description
The potential involvement of the solvent in heterolytic Co-C bond cleavage for vitamin B12 derivatives has been probed by measuring for the first time activation parameters for heterolytic Co-C bond cleavage. If a water molecule is part of the transition
Collections | ANU Research Publications |
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Date published: | 2003 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/74253 |
Source: | Dalton Transactions |
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