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Mechanistic insight from activation parameters for the reaction between co-enzyme B 12 and cyanide: further evidence that heterolytic Co�C bond cleavage is solvent-assisted.

Hamza, Mohamed; Cregan, Andrew; Brasch, Nicola E; van Eldik, Rudi


The potential involvement of the solvent in heterolytic Co-C bond cleavage for vitamin B12 derivatives has been probed by measuring for the first time activation parameters for heterolytic Co-C bond cleavage. If a water molecule is part of the transition

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Dalton Transactions


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