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Reversible aqueous metathesis reactions for potential application in dynamic combinatorial chemistry

Hunter, Luke; Condie, Glenn C; Harding, Margaret

Description

Solutions of heterocycles having an allyl sulfide unit and simple alkenes in 50% t-BuOH/H2O undergo reversible olefin metathesis reactions with the second generation Hoveyda-Grubbs catalyst. The choice of functional groups is limited by competitive chelation of some heterocycles with the catalyst, and other stereoelectronic effects.

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
URI: http://hdl.handle.net/1885/73600
Source: Tetrahedron Letters
DOI: 10.1016/j.tetlet.2010.07.105

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