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Synthesis and X-ray crystallographic analysis of chiral pyridyl substituted carbocyclic molecular clefts

Lee, Connie K Y; Groneman, Jennifer L; Turner, Peter; Rendina, Lou; Harding, Margaret

Description

Ditopic symmetrical bis(pyridyl) ligands incorporating the chiral dibenzobicyclo[b,f][3.3.1]nona-5a,6a-diene-6,12-dione cleft have been synthesised and characterised by NMR spectroscopy, mass spectrometry and X-ray crystallography. The ligands, which incorporate pyridyl groups directly connected to the carbocyclic cleft core or via alkyne or phenyl linkers were accessed from palladium-catalysed coupling reactions of 2,8-dibromodibenzobicyclo[b,f][3.3.1]nona-5a,6a-diene-6,12-dione. X-ray crystal...[Show more]

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
URI: http://hdl.handle.net/1885/73572
Source: Tetrahedron
DOI: 10.1016/j.tet.2006.03.014

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