Ligand self-recognition in the stereoselective assembly of [2 + 2] metallomacrocycles from racemic chiral bisbipyridyl molecular clefts and zinc(II)
The synthesis of racemic and optically pure ligand L, in which two 6,6′-disubstituted bipyridines are connected by methyleneoxy linkers to the molecular cleft dibenzobicyclo[b,f][3.3.1.]nona-5a,6a-diene-6,12-dione, is reported. In the presence of 2 equi
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