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Assignment of the 13 C and 15 N NMR spectra of the antitumour antibiotic streptonigrin

Harding, Margaret; Anderberg, Pia I; Luck, Ian J

Description

The assignments of the two pyridyl nitrogens and two amino nitrogens in the antitumour antibiotic streptonigrin, and all carbon resonances, were determined by 15N (HSQC, HMBC) and 13C (HSQC, HMBC) NMR techniques. These data provide useful probes for determination of the site(s) of metal complexation in the drug, which are important in the mechanism of antitumour activity.

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
URI: http://hdl.handle.net/1885/73519
Source: Magnetic Resonance in Chemistry
DOI: 10.1002/mrc.997

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